Laboratory for Chemistry and Life Science, Institute of Integrated Research, Institute of Science Tokyo

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  • 2026.02.19

Chiralization of metal-containing dyes upon mere encapsulation

New molecular capsules capable of imparting chiral activity to non-chiral metal-containing dyes were successfully created by self-assembly in water, as reported by researchers from Japan. These capsules have adaptable chiral cavities, inducing chirality of various large and rigid metal-containing dyes upon encapsulation, without requiring typical chemical modification. Moreover, the chiral properties can be tuned with heat, showcasing the potential use in chiral materials and catalysts.

Reference

●Authors Yoshihisa Hashimoto, Yuya Tanaka*, Si-Yu Liu, Hiroshi Shinokubo, and Michito Yoshizawa*
●Title Chiral Aromatic Micelles as Chiroptical Host Tools for Large Metallodyes in Water
●Journal Journal of the American Chemical Society
●First published June 15, 2025
●DOI 10.1021/jacs.5c06179

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